fac-Aquadichloridotris(tetramethylene sulfoxide-κS)ruthenium(II)
| Autor: | Frank R. Fronczek, Carlos F. Gonzales, Radhey S. Srivastava |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2009 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 65, Iss 2, Pp m170-m170 (2009) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S1600536809000439 |
| Popis: | The title molecule, [RuCl2(C4H8OS)3(H2O)], is the isomer with the two chloride ligands cis and the three S-coordinated tetramethylene sulfoxide ligands facial relative to the Ru(II) center. The Ru—Cl distances are 2.4161 (7) and 2.4317 (7) Å, the Ru—O distance is 2.1540 (19) Å, and the Ru—S distances are in the range 2.2254 (8)–2.2657 (7) Å, with the shortest being that trans to the aqua ligand. The coordinated water molecule forms intermolecular hydrogen bonds with Cl and sulfoxide O atoms. |
| Databáze: | Directory of Open Access Journals |
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