Isotherm and Kinetics of Fe(II) Adsorption onto Chitosan in a Batch Process

Autor: Hamideh Radnia, Ali Asghar Ghoreyshi, Habibollah Younesi
Jazyk: angličtina
Rok vydání: 2011
Předmět:
Zdroj: Iranica Journal of Energy and Environment, Vol 2, Iss 3, Pp 250-257 (2011)
Druh dokumentu: article
ISSN: 2079-2115
2079-2123
Popis: In this study removal of Fe(II) by chitosan adsorbent was experimentally investigated in a batch system. The adsorbent dose and pH of the metal solution was fixed at 0.15 g and 4, respectively. Adsorption experiments were carried out at initial concentration range of 10–50 mg l-1 at 20˚C. Equilibrium studies showed that experimental data were well fitted to Langmuir–Freundlich isotherm model. Linear and non-linear forms of pseudo-first-order and pseudo-second-order kinetic models were employed to describe the kinetic adsorption processes. The model parameters were confidently recovered. The kinetics followed the non-linear form of pseudo-first-order model which represents adsorption of Fe(II) on chitosan takes place through a physical process. The examination of kinetic data also revealed that the adsorption rate was dominated by intra-particle diffusion mechanism.
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