Rapid transformation of sulfinate salts into sulfonates promoted by a hypervalent iodine(III) reagent

Autor: Elsa Deruer, Vincent Hamel, Samuel Blais, Sylvain Canesi
Jazyk: angličtina
Rok vydání: 2018
Předmět:
Zdroj: Beilstein Journal of Organic Chemistry, Vol 14, Iss 1, Pp 1203-1207 (2018)
Druh dokumentu: article
ISSN: 1860-5397
DOI: 10.3762/bjoc.14.101
Popis: An alternative method for forming sulfonates through hypervalent iodine(III) reagent-mediated oxidation of sodium sulfinates has been developed. This transformation involves trapping reactive sulfonium species using alcohols. With additional optimization of the reaction conditions, the method appears extendable to other nucleophiles such as electron-rich aromatic systems or cyclic ethers through a ring opening pathway.
Databáze: Directory of Open Access Journals