A curved host and second guest cooperatively inhibit the dynamic motion of corannulene

Autor: Yang Yang, Tanya K. Ronson, Zifei Lu, Jieyu Zheng, Nicolas Vanthuyne, Alexandre Martinez, Jonathan R. Nitschke
Jazyk: angličtina
Rok vydání: 2021
Předmět:
Zdroj: Nature Communications, Vol 12, Iss 1, Pp 1-8 (2021)
Druh dokumentu: article
ISSN: 2041-1723
DOI: 10.1038/s41467-021-24344-w
Popis: The preparation of artificial host–guest systems that display dynamic adaptation during guest binding is challenging. Here the authors report a chiral self-assembled tetrahedral cage featuring curved walls that reconfigures stereochemically to fit fullerene guests, regulates corannulene inversion, and enables the determination of co-guest enantiomeric excess by NMR spectroscopy.
Databáze: Directory of Open Access Journals
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