Ionic Polymer Microactuator Activated by Photoresponsive Organic Proton Pumps

Autor: Khaled M. Al-Aribe, George K. Knopf, Amarjeet S. Bassi
Jazyk: angličtina
Rok vydání: 2015
Předmět:
Zdroj: Actuators, Vol 4, Iss 4, Pp 237-254 (2015)
Druh dokumentu: article
ISSN: 2076-0825
DOI: 10.3390/act4040237
Popis: An ionic polymer microactuator driven by an organic photoelectric proton pump transducer is described in this paper. The light responsive transducer is fabricated by using molecular self-assembly to immobilize oriented bacteriorhodopsin purple membrane (PM) patches on a bio-functionalized porous anodic alumina (PAA) substrate. When exposed to visible light, the PM proton pumps produce a unidirectional flow of ions through the structure’s nano-pores and alter the pH of the working solution in a microfluidic device. The change in pH is sufficient to generate an osmotic pressure difference across a hydroxyethyl methacrylate-acrylic acid (HEMA-AA) actuator shell and induce volume expansion or contraction. Experiments show that the transducer can generate an ionic gradient of 2.5 μM and ionic potential of 25 mV, producing a pH increase of 0.42 in the working solution. The ΔpH is sufficient to increase the volume of the HEMA-AA microactuator by 80%. The volumetric transformation of the hydrogel can be used as a valve to close a fluid transport micro-channel or apply minute force to a mechanically flexible microcantilever beam.
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