catena-Poly[[diaquazinc(II)]-μ-l-cysteinato(2−)-κ4S:S,N,O-[di-μ-sulfido-bis[oxidomolybdate(V)](Mo—Mo)]-μ-l-cysteinato(2−)-κ4S,N,O:S]
| Autor: | Genta Sakane, Shinobu Ogasahara, Takashi Shibahara |
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| Jazyk: | angličtina |
| Rok vydání: | 2008 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 64, Iss 5, Pp m605-m606 (2008) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S1600536808007757 |
| Popis: | The title compound, [Mo2Zn(C3H5NO2S)2O2S2(H2O)2], forms a one-dimensional chain. The cysteine S atom of the dinuclear molybdenum complex anion coordinates to the zinc ion, which has a tetrahedral environment by the additional coordination of two water molecules. The one-dimensional chains are connected to each other by hydrogen bonds. The Zn—S(cysteine) distances [2.3599 (6) and 2.3072 (6) Å] are close to the value in ZnS (2.35 Å). The distances and angles within the complex are very close to those reported for the sodium and potassium di-μ-sulfide species. |
| Databáze: | Directory of Open Access Journals |
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