Deposition nucleation on mineral dust particles: a case against classical nucleation theory with the assumption of a single contact angle
| Autor: | M. J. Wheeler, A. K. Bertram |
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| Jazyk: | angličtina |
| Rok vydání: | 2012 |
| Předmět: | |
| Zdroj: | Atmospheric Chemistry and Physics, Vol 12, Iss 2, Pp 1189-1201 (2012) |
| Druh dokumentu: | article |
| ISSN: | 1680-7316 1680-7324 |
| DOI: | 10.5194/acp-12-1189-2012 |
| Popis: | Deposition nucleation on two mineral species, kaolinite and illite, was studied using a flow cell coupled to an optical microscope. The results show that the Sice conditions when ice first nucleated, defined as the onset Sice (Sice,onset), is a strong function of the surface area available for nucleation, varying from 100% to 125% at temperatures between 242 and 239 K. The surface area dependent data could not be described accurately using classical nucleation theory and the assumption of a single contact angle (defined here as the single-α model). These results suggest that caution should be applied when using contact angles determined from Sice,onset data and the single-α model. In contrast to the single-α model, the active site model, the deterministic model, and a model with a distribution of contact angles fit the data within experimental uncertainties. Parameters from the fits to the data are presented. |
| Databáze: | Directory of Open Access Journals |
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