Synthesis and crystal structure of an oxorhenium(V) complex containing a tridentate imidazole ligand
| Autor: | Zenixole R. Tshentu, Thomas I.A. Gerber, Peter Mayer |
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| Jazyk: | angličtina |
| Rok vydání: | 2007 |
| Předmět: | |
| Zdroj: | Bulletin of the Chemical Society of Ethiopia, Vol 21, Iss 1, Pp 75-81 (2007) |
| Druh dokumentu: | article |
| ISSN: | 1011-3924 1726-801X |
| Popis: | The reaction of equimolar amounts of (n-Bu4N)[ReOCl4] and 2-(1-ethanolthiomethyl)-1-methylimidazole (Htmi)in acetonitrile yielded cis-[ReOCl2(tmi)]. An X-ray diffraction study shows that tmiˉ coordinates as a uninegative N,S,O-tridentate ligand to give distorted octahedral geometry around the rhenium(V) ion. The three donor atoms occupy a triangular face in an octahedron, with the alcoholate oxygen coordinated trans to the oxo group. |
| Databáze: | Directory of Open Access Journals |
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