| Autor: |
GUO Wen-ming, ZHANG Yan-ling, LIU Yang, JIA Xin-lei |
| Jazyk: |
čínština |
| Rok vydání: |
2015 |
| Předmět: |
|
| Zdroj: |
工程科学学报, Vol 37, Iss 10, Pp 1296-1304 (2015) |
| Druh dokumentu: |
article |
| ISSN: |
2095-9389 |
| DOI: |
10.13374/j.issn2095-9389.2015.10.007 |
| Popis: |
The effect of various states of Fe(Fe,FeO,and Fe2O3) on the reduction of Cr2O3 was investigated by conducting isothermal experiments on the reduction of Fe-Cr2O3,Fe2O3-Cr2O3 and FeCr2O4 by graphite at 1350-1550℃ combined with X-ray diffraction and scanning electron microscopy with energy-dispersive spectrometry. It is shown that the tendency of final reduction degree is Fe2O3-Cr2O3-C 〉 FeCr2O4-C 〉 Fe-Cr2O3-C at each temperature,and the transformation path of the three samples is oxides → carbides → Fe-Cr-C alloy. Liquid alloy which earlier emerges and low carbon-content carbides promote the reduction of Fe2O3-Cr2O3. Low carbon dissolution in liquid alloy limits the reduction degree of FeCr2O4. The large amount of carbides and little liquid alloy retard the reduction of Fe-Cr2O3. The apparent activation energies of Fe-Cr2O3-C,FeCr2O4-C and Fe2O3-Cr2O3-C are 142.90,111.84 and 128.9 kJ·mol-1,respectively. |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
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