Crystal structure of 4-amino-1-(4-methylbenzyl)pyridinium bromide

Autor: N. Sharmila, T. V. Sundar, A. Yasodha, A. Puratchikody, B. Sridhar
Jazyk: angličtina
Rok vydání: 2014
Předmět:
Zdroj: Acta Crystallographica Section E, Vol 70, Iss 12, Pp o1293-o1294 (2014)
Druh dokumentu: article
ISSN: 1600-5368
16005368
DOI: 10.1107/S1600536814025343
Popis: The title molecular salt, C13H15N2+·Br−, crystallized with two independent ion pairs (A and B) in the asymmetric unit. In the cations, the planes of the pyridine and benzene rings are inclined to one another by 79.32 (8) and 82.30 (10)° in ion pairs A and B, respectively. In the crystal, the anions and cations are connected by N—H...Br hydrogen bonds, forming a centrosymmetric tetramer-like unit enclosing an R84(16) ring motif. These units are linked via C—H...Br hydrogen bonds, forming a three-dimensional network.
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