Aqua(2-oxido-2,2-diphenylacetato-κ2O1,O2)(1,10-phenanthroline-κ2N,N′)copper(II)
| Autor: | Xiao-Xia Yang, Fu-Yong Zhang, Shi-Hai Xu |
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| Jazyk: | angličtina |
| Rok vydání: | 2010 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 66, Iss 1, Pp m69-m69 (2010) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S1600536809053483 |
| Popis: | In the title mononuclear complex, [Cu(C14H10O3)(C12H8N2)(H2O)], the CuII atom is five-coordinated by two N atoms from a 1,10-phenanthroline (phen) ligand, two O atoms from a benzilate ligand and one O atom from a water molecule in a distorted square-pyramidal geometry. The crystal structure is stabilized via intermolecular O—H...O and C—H...O hydrogen bonds, C—H...π interactions and π–π stacking interactions between the pyridine and benzene rings of neighboring phen ligands [centroid–centroid distances = 3.684 (2), 3.564 (2) and 3.380 (1) Å]. |
| Databáze: | Directory of Open Access Journals |
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