The thermolysis of ruthenium(II, III) ammine complexes in water solutions at the increased temperatures and the solid phase.
| Autor: | E. V. Fesik, V. V. Grebnev, G. D. Malchikov |
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| Jazyk: | ruština |
| Rok vydání: | 2008 |
| Předmět: | |
| Zdroj: | Тонкие химические технологии, Vol 3, Iss 3, Pp 73-77 (2008) |
| Druh dokumentu: | article |
| ISSN: | 2410-6593 2686-7575 |
| Popis: | In this work reactions of the hexaammine ruthenium(II) - [Ru(NH3)6]Cl2 and “ruthenium red” -[Ru3O2(NH3)14]Cl6 • 4Н2О chlorides in the water alkaline solution at 190˚С (autoclave) and in the solid phase are investigated. The mechanism of restoration of the ruthenium ion by inside sphere ammonia up to the metal condition is offered. |
| Databáze: | Directory of Open Access Journals |
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