Photocatalytic activity of CuInS2 nanoparticles synthesized via a simple and rapid microwave heating process

Autor: Nawapong Chumha, Watcharapong Pudkon, Auttaphon Chachvalvutikul, Tawanwit Luangwanta, Chamnan Randorn, Burapat Inceesungvorn, Athipong Ngamjarurojana, Sulawan Kaowphong
Jazyk: angličtina
Rok vydání: 2020
Předmět:
Zdroj: Materials Research Express, Vol 7, Iss 1, p 015074 (2020)
Druh dokumentu: article
ISSN: 2053-1591
DOI: 10.1088/2053-1591/ab6885
Popis: In this research, visible–light photocatalytic activities of CuInS _2 nanoparticles for degradation of three organic dyes (rhodamine B; RhB, methylene blue; MB, and methyl orange; MO) were investigated. The CuInS _2 nanoparticles were synthesized by a simple and rapid microwave heating process using sodium sulfide as a sulfur source and then characterized by x–ray diffraction (XRD), field emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM), Brunauer–Emmett–Teller (BET), and UV–vis diffuse reflectance spectroscopy (UV–vis DRS) techniques. The synthesized CuInS _2 nanoparticles exhibited excellent photocatalytic degradation activity to the cationic dyes (RhB and MB) when compared with that of anionic dye (MO). Zeta potential of the CuInS _2 photocatalyst was measured to elucidate the adsorption ability toward dye molecules. A possible photocatalytic degradation mechanism was proposed based on active species quenching experiments and Mott–Schottky analysis.
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