| Autor: |
Iñaki Gomez, Yolanda Alesanco, Jose Alberto Blázquez, Ana Viñuales, Luis C. Colmenares |
| Jazyk: |
angličtina |
| Rok vydání: |
2020 |
| Předmět: |
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| Zdroj: |
Polymers, Vol 12, Iss 11, p 2686 (2020) |
| Druh dokumentu: |
article |
| ISSN: |
2073-4360 |
| DOI: |
10.3390/polym12112686 |
| Popis: |
The trend of research towards more sustainable materials is pushing the application of biopolymers in a variety of unexplored fields. In this regard, hydrogels are attracting significant attention as electrolytes for flexible electrochemical devices thanks to their combination of ionic conductivity and mechanical properties. In this context, we present the use of cellulose-based hydrogels as aqueous electrolytes for electrochemical devices. These materials were obtained by crosslinking of hydroxyethyl cellulose (HEC) with divinyl sulfone (DVS) in the presence of carboxymethyl cellulose (CMC), creating a semi-IPN structure. The reaction was confirmed by NMR and FTIR. The small-amplitude oscillatory shear (SAOS) technique revealed that the rheological properties could be conveniently varied by simply changing the gel composition. Additionally, the hydrogels presented high ionic conductivity in the range of mS cm−1. The ease of synthesis and processing of the hydrogels allowed the assembly of an all-in-one electrochromic device (ECD) with high transmittance variation, improved switching time and good color efficiency. On the other hand, the swelling ability of the hydrogels permits the tuning of the electrolyte to improve the performance of a printed Zinc/MnO2 primary battery. The results prove the potential of cellulose-based hydrogels as electrolytes for more sustainable electrochemical devices. |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
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