Tailoring size and fraction of coherent L12 nanoprecipitates to achieve strong hardening in medium entropy alloys with heterogeneous grain structures

Autor: Guohao Qin, Zihan Zhang, Wei Wang, Xiaolei Wu, Fuping Yuan
Jazyk: angličtina
Rok vydání: 2024
Předmět:
Zdroj: Journal of Materials Research and Technology, Vol 32, Iss , Pp 2963-2971 (2024)
Druh dokumentu: article
ISSN: 2238-7854
DOI: 10.1016/j.jmrt.2024.08.106
Popis: Heterogeneous grain structures with coherent L12 nanoprecipitates were constructed in a medium entropy alloy with chemical composition of Co34.5Cr32Ni27.5Al3Ti3 (at. %). The volume fraction and size of L12 nanoprecipitates are observed to become higher and larger, and the interspacing is found to become smaller with increasing aging time, resulting in a severer heterogeneity. The domain of tensile properties was expanded by varying the size and volume fraction of coherent L12 nanoprecipitates after aging treatment. The samples after longer-time aging treatment show stronger strain hardening as compared to those after shorter-time aging treatment. The hetero-deformation-induced (HDI) hardening plays a more vital role in the longer-time aged samples than the shorter-time aged samples, especially at the elasto-plastic transition stage. The dominant precipitation hardening mechanism is observed to transit from dislocation-cutting to Orowan dislocation-looping with increasing precipitation size, as predicted by a theoretical model and validated by experimental results. Multiple deformation defects, such as deformation twins, stacking faults and Lomer-Cottrell locks, are the dominant deformation mechanisms for all samples, while interactions between these defects and L12 nanoprecipitates were observed to be more intensive in the longer-time aged samples than in the shorter-time aged samples, resulting in stronger precipitation and HDI hardening.
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