Nickel(0)-catalyzed divergent reactions of silacyclobutanes with internal alkynes

Autor: Xi-Chao Wang, Bo Li, Cheng-Wei Ju, Dongbing Zhao
Jazyk: angličtina
Rok vydání: 2022
Předmět:
Zdroj: Nature Communications, Vol 13, Iss 1, Pp 1-11 (2022)
Druh dokumentu: article
ISSN: 2041-1723
DOI: 10.1038/s41467-022-31006-y
Popis: Transition metal-catalyzed reactions of silacyclobutanes to access structurally diverse organosilicon compounds have attracted attention in recent years. Here, the authors show nickel-catalysed, ligand-controlled chemodivergent reactions of these compounds with alkynes to (benzo)silacyclohexenes and allyl vinylsilane.
Databáze: Directory of Open Access Journals