A two-dimensional organic–inorganic hybrid compound, poly[(ethylenediamine)tri-μ-oxido-oxidocopper(II)molybdenum(VI)]
| Autor: | Mehtap Emirdag-Eanes, Don VanDerveer, Ozgul Gun |
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| Jazyk: | angličtina |
| Rok vydání: | 2008 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 64, Iss 10, Pp m1238-m1239 (2008) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 00734039 |
| DOI: | 10.1107/S160053680802792X |
| Popis: | A new organic–inorganic two-dimensional hybrid compound, [CuMoO4(C2H8N2)], has been hydrothermally synthesized at 443 K. The unit cell contains layers composed of CuN2O4 octahedra and MoO4 tetrahedra. Corner-sharing MoO4 and CuN2O4 polyhedra form CuMoO4 bimetallic sites that are joined together through O atoms, forming an edge-sharing Cu2Mo2O4 chain along the c axis. The one-dimensional chains are further linked through bridging O atoms that join the Cu and Mo atoms into respective chains along the b axis, thus establishing layers in the bc plane. The ethylenediamine ligand is coordinated to the Cu atom through its two N atoms and is oriented perpendicularly to the two-dimensional –Cu—O—Mo– layers. The average distance between adjacent layers, as calculated by consideration of the closest and furthest distances between two layers, is 8.7 Å. The oxidation states of the Mo and Cu atoms of VI and II, respectively, were confirmed by bond-valence sum calculations. |
| Databáze: | Directory of Open Access Journals |
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