A simple and rapid colorimetric detection of methanol, ethanol, and isopropanol and its application toward alcohol-based hand sanitizer quality control

Autor: Warongrit Sukma, Cheerapa Boonyakong, Thitiphan Chaiphet, Supakarn Chamni
Jazyk: angličtina
Rok vydání: 2024
Předmět:
Zdroj: Green Chemistry Letters and Reviews, Vol 17, Iss 1 (2024)
Druh dokumentu: article
ISSN: 17518253
1751-7192
1751-8253
DOI: 10.1080/17518253.2023.2298982
Popis: ABSTRACTA practical colorimetric analysis for alcohol determination was devised using a composite of food colorants, specifically a green solution of brilliant blue FCF and tartrazine at a ratio of 1:5 v/v. This colorimetric method was characterized by its simplicity, user-friendliness, environmental compatibility, cost-effectiveness, and suitability for self-measurement through visual examination. The colorimetric procedure entails admixture 1 mL of the alcohol sample with 50 µL of the green test solution and 250 µL of a 30% NaOH solution at ambient temperature. The ensuing color changes were visually assessed within 5 min. Through color sensing, methanol, ethanol, and isopropanol were identified by the manifestation of lemon yellow, orange, and biphasic solutions, respectively. Ethanol was semi-quantified based on color sensing from green to orange, with corresponding concentration ranges. The limit of detection for both methanol and ethanol was determined to be 30% v/v. The developed method demonstrated an accuracy of 93%, with the error range of 1 − 10% v/v and standard deviation of 3.9% v/v, as confirmed by the analysis of 100 commercially available alcohol-based hand sanitizers. This methodology has the potential for further expansion to encompass a wide range of rapid colorimetric analyses of products containing alcohol, including food items, alcohol raw materials, and cosmetics.
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