Enhanced Gas-Sensing Performance of GO/TiO2 Composite by Photocatalysis

Autor: Eunji Lee, Doohee Lee, Jaesik Yoon, Yilin Yin, You Na Lee, Sunil Uprety, Young Soo Yoon, Dong-Joo Kim
Jazyk: angličtina
Rok vydání: 2018
Předmět:
Zdroj: Sensors, Vol 18, Iss 10, p 3334 (2018)
Druh dokumentu: article
ISSN: 1424-8220
DOI: 10.3390/s18103334
Popis: Few studies have investigated the gas-sensing properties of graphene oxide/titanium dioxide (GO/TiO2) composite combined with photocatalytic effect. Room temperature gas-sensing properties of the GO/TiO2 composite were investigated towards various reducing gases. The composite sensor showed an enhanced gas response and a faster recovery time than a pure GO sensor due to the synergistic effect of the hybridization, such as creation of a hetero-junction at the interface and modulation of charge carrier density. However, the issue of long-term stability at room temperature still remains unsolved even after construction of a composite structure. To address this issue, the surface and hetero-junction of the GO/TiO2 composite were engineered via a UV process. A photocatalytic effect of TiO2 induced the reduction of the GO phase in the composite solution. The comparison of gas-sensing properties before and after the UV process clearly showed the transition from n-type to p-type gas-sensing behavior toward reducing gases. This transition revealed that the dominant sensing material is GO, and TiO2 enhanced the gas reaction by providing more reactive sites. With a UV-treated composite sensor, the function of identifying target gas was maintained over a one-month period, showing strong resistance to humidity.
Databáze: Directory of Open Access Journals
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