(5R)-5-[(1R)-2,2-Dichloro-1-methylcyclopropyl]-2-methylcyclohex-2-en-1-one
Autor: | Brahim Boualy, Mohamed Anoir Harrad, Larbi El Firdoussi, Mustapha Ait Ali, Corrado Rizzoli |
---|---|
Jazyk: | angličtina |
Rok vydání: | 2011 |
Předmět: | |
Zdroj: | Acta Crystallographica Section E, Vol 67, Iss 7, Pp o1638-o1638 (2011) |
Druh dokumentu: | article |
ISSN: | 16005368 1600-5368 |
DOI: | 10.1107/S1600536811021933 |
Popis: | The title compound, C11H14Cl2O, was synthesized by the reaction of a dichloromethane solution of (R)-carvone and potassium tert-butanolate in the presence of a catalytic amount of benzyltriethylammonium chloride in chloroform. The cyclohexene ring adopts a half-boat conformation. The cyclopropyl ring is unsymmetrical, the shortest C—C bond being distal to the alkyl-substituted C atom. The crystal packing is stabilized only by van der Waals interactions. |
Databáze: | Directory of Open Access Journals |
Externí odkaz: |