(5R)-5-[(1R)-2,2-Dichloro-1-methylcyclopropyl]-2-methylcyclohex-2-en-1-one

Autor: Brahim Boualy, Mohamed Anoir Harrad, Larbi El Firdoussi, Mustapha Ait Ali, Corrado Rizzoli
Jazyk: angličtina
Rok vydání: 2011
Předmět:
Zdroj: Acta Crystallographica Section E, Vol 67, Iss 7, Pp o1638-o1638 (2011)
Druh dokumentu: article
ISSN: 16005368
1600-5368
DOI: 10.1107/S1600536811021933
Popis: The title compound, C11H14Cl2O, was synthesized by the reaction of a dichloromethane solution of (R)-carvone and potassium tert-butanolate in the presence of a catalytic amount of benzyltriethylammonium chloride in chloroform. The cyclohexene ring adopts a half-boat conformation. The cyclopropyl ring is unsymmetrical, the shortest C—C bond being distal to the alkyl-substituted C atom. The crystal packing is stabilized only by van der Waals interactions.
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