Cobaltoceniumsulfonate
| Autor: | Stefan Vanicek, Klaus Wurst, Benno Bildstein |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2017 |
| Předmět: | |
| Zdroj: | IUCrData, Vol 2, Iss 11, p x171703 (2017) |
| Druh dokumentu: | article |
| ISSN: | 2414-3146 24143146 |
| DOI: | 10.1107/S2414314617017035 |
| Popis: | The title compound, [Co(C5H5)(C5H4O3S)], was synthesized by dediazoniation of cobaltoceniumdiazonium bis(hexafluoridophosphate) with CuCl and SO2, crystallizing as yellow platelets. Structurally, a regular cobaltocenium sandwich moiety is observed containing coplanar cyclopentadienyl rings and displaying unexceptional carbon–cobalt [2.0230 (16)–2.0452 (14) Å] and carbon–carbon [1.410 (3)–1.431 (3) Å] bond distances. In this mesoionic molecule, the cationic cobaltoceniumyl part is connected to its anionic sulfonate part by a carbon–sulfur single bond of 1.7717 (15) Å. |
| Databáze: | Directory of Open Access Journals |
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