1-Benzoyl-3,3-bis(propan-2-yl)thiourea
| Autor: | N. Gunasekaran, R. Karvembu, Seik Weng Ng, Edward R. T. Tiekink |
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| Jazyk: | angličtina |
| Rok vydání: | 2010 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 66, Iss 8, Pp o2113-o2113 (2010) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S1600536810028862 |
| Popis: | Two independent thiourea derivatives comprise the asymmetric unit of the title compound, C14H20N2OS. The major difference between the molecules relates to a twist in the relative orientation of the benzene rings [torsion angles = 4.5 (2) and −19.9 (2)° for the two independent molecules]. The thiocarbonyl and carbonyl groups lie to opposite sides of the molecule as there are twists about the central N—S bond [torsion angles = 83.90 (15) and 81.77 (15)°]. Supramolecular chains extending parallel to [101] with a stepped topology and mediated by N—H...O hydrogen bonding feature in the crystal structure. C—H...O and C—H...π interactions are also present. |
| Databáze: | Directory of Open Access Journals |
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