Enantioselective Cu-catalyzed double hydroboration of alkynes to access chiral gem-diborylalkanes

Autor: Shengnan Jin, Jinxia Li, Kang Liu, Wei-Yi Ding, Shuai Wang, Xiujuan Huang, Xue Li, Peiyuan Yu, Qiuling Song
Jazyk: angličtina
Rok vydání: 2022
Předmět:
Zdroj: Nature Communications, Vol 13, Iss 1, Pp 1-12 (2022)
Druh dokumentu: article
ISSN: 2041-1723
DOI: 10.1038/s41467-022-31234-2
Popis: Optically enriched 1,1-diboron compounds are significantly underdeveloped because of the paucity of the straightforward synthetic protocols. Herein, the authors report an enantioselective copper-catalyzed cascade double hydroboration of terminal alkynes to access highly enantioenriched gem-diborylalkanes.
Databáze: Directory of Open Access Journals