Crystal structure of 3-[(E)-(2-hydroxy-3-methoxybenzylidene)amino]-1-methyl-1-phenylthiourea
| Autor: | Rajeswari Gangadharan, Mathiyan Muralisankar, Anandaram Sreekanth, Abdullakutty Anees Rahman, K. Sethusankar |
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| Jazyk: | angličtina |
| Rok vydání: | 2016 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E: Crystallographic Communications, Vol 72, Iss 5, Pp 608-611 (2016) |
| Druh dokumentu: | article |
| ISSN: | 2056-9890 20569890 |
| DOI: | 10.1107/S2056989016005326 |
| Popis: | In the asymmetric unit of the title compound, C16H17N3O2S, there are two independent molecules (A and B), which show an E conformation with respect to the C=N bond. An intramolecular O—H...N hydrogen bond with an S(6) motif stabilizes the molecular structure. The terminal phenyl and benzene rings are almost orthogonal to each other, the dihedral angle being 87.47 (13)° for molecule A and 89.86 (17)° for molecule B. In the crystal, weak bifurcated N—H...(O,O) hydrogen bonds link the two independent molecules, forming a supramolecular chain with a C21(14)[R21(5)] motif along the b axis. A weak C—H...O interaction is also observed in the chain. |
| Databáze: | Directory of Open Access Journals |
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