Direct and selective access to amino-poly(phenylene vinylenes)s with switchable properties by dimerizing polymerization of aminoaryl carbenes

Autor: Quentin Sobczak, Aravindu Kunche, Damien Magis, Daiann Sosa Carrizo, Karinne Miqueu, Jean-Marc Sotiropoulos, Eric Cloutet, Cyril Brochon, Yannick Landais, Daniel Taton, Joan Vignolle
Jazyk: angličtina
Rok vydání: 2021
Předmět:
Zdroj: Nature Communications, Vol 12, Iss 1, Pp 1-8 (2021)
Druh dokumentu: article
ISSN: 2041-1723
DOI: 10.1038/s41467-021-24274-7
Popis: Despite the ubiquity of singlet carbenes in chemistry, their utility as true monomeric building blocks for the synthesis of functional organic polymers has been underexplored. Here the authors show mono- and bis-acyclic amino(aryl)carbenes selectively dimerize to form diaminoalkenes and hitherto unknown amino-containing poly(p-phenylene vinylene)s.
Databáze: Directory of Open Access Journals
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