Tetrachlorido(1,10-phenanthroline-κ2N,N′)platinum(IV) acetonitrile hemisolvate
| Autor: | Kwang Ha, In-Chul Hwang, Nam-Ho Kim |
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| Jazyk: | angličtina |
| Rok vydání: | 2009 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 65, Iss 2, Pp m224-m224 (2009) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S1600536809002359 |
| Popis: | The asymmetric unit of the title compound, [PtCl4(C12H8N2)]·0.5CH3CN, contains two crystallographically independent PtIV complexes with very similar geometry and one solvent molecule. In the complexes, each PtIV ion is six-coordinated in a distorted octahedral environment by two N atoms of the 1,10-phenanthroline ligand and four Cl atoms. Because of the different trans effects of the N and Cl atoms, the Pt—Cl bonds trans to the N atom are slightly shorter than those trans to the Cl atom. The compound displays numerous intermolecular π–π interactions between six-membered rings, with a shortest centroid-to-centroid distance of 3.654 Å. There are also weak intra- and intermolecular C—H...Cl hydrogen bonds. |
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