Reductive dearomative arylcarboxylation of indoles with CO2 via visible-light photoredox catalysis

Autor: Wen-Jun Zhou, Zhe-Hao Wang, Li-Li Liao, Yuan-Xu Jiang, Ke-Gong Cao, Tao Ju, Yiwen Li, Guang-Mei Cao, Da-Gang Yu
Jazyk: angličtina
Rok vydání: 2020
Předmět:
Zdroj: Nature Communications, Vol 11, Iss 1, Pp 1-9 (2020)
Druh dokumentu: article
ISSN: 2041-1723
DOI: 10.1038/s41467-020-17085-9
Popis: Catalytic reductive coupling of two electrophiles and one C = C bond is usually performed by two electron transfer metal catalysis. Herein, the authors show a visible light photoredox-catalyzed successive single electron transfer leading to dearomative arylcarboxylation of indoles with CO2 and generating indoline-3-carboxylic acids.
Databáze: Directory of Open Access Journals