Electrochemical Oxidation of Fragrances 4-Allyl and 4-Propenylbenzenes on Platinum and Carbon Paste Electrodes

Autor:	Lai-Hao Wang, Chia-Ling Chang, Yi-Chun Hu
Jazyk:	angličtina
Rok vydání:	2015
Předmět:	Chemistry QD1-999
Zdroj:	Croatica Chemica Acta, Vol 88, Iss 1, Pp 35-42 (2015)
Druh dokumentu:	article
ISSN:	0011-1643 1334-417X
DOI:	10.5562/cca2342
Popis:	The electrochemical oxidation behaviors of 4-allylbenzenes (estragole, safrole and eugenol) and 4-propenylbenzenes (anethole, asarone and isoeugenol) on platinum and carbon paste electrodes were investigated in a Britton-Robinson buffer (pH = 2.93 and 10.93), acetate buffer, phosphate buffer solutions (pH = 2.19 and 6.67), and acetonitrile containing various supporting electrolytes examined lithium perchlorate. Their oxidation potential with Hammett (free-energy relationships) and possible reaction mechanisms were discussed.
Databáze:	Directory of Open Access Journals
Externí odkaz:	https://doaj.org/article/51fddcc8d0e34e8ea8a9c8f42d7d48f0 Zobrazit plný text záznamu View record in DOAJ Plný text ve formátu PDF