(Acetylacetonato-κ2O,O′)aqua[salicylaldehyde nicotinoylhydrazonato(2−)-κ3O,N,O′]manganese(III)
| Autor: | Zhong-Wu Fu, Shi-Xiong Liu, Zeng-You Wang |
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| Jazyk: | angličtina |
| Rok vydání: | 2008 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 64, Iss 2, Pp m371-m372 (2008) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S1600536807060734 |
| Popis: | The MnIII atom in the title complex, [Mn(C13H9N3O2)(C5H7O2)(H2O)], is coordinated by three donors from a dianionic ligand, salicylaldehyde nicotylhydrazone, two O atoms from an acetylacetonate anion and a water molecule in a distorted octahedral geometry. There is an extended two-dimensional supramolecular motif resulting from O—H...N hydrogen bonds between the coordinated water molecule and a hydrazine N or pyridine N atom, and from C—H...O hydrogen bonds between a CH group and the phenolate O atom. |
| Databáze: | Directory of Open Access Journals |
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