Influence of the Pore Diameter on the Adsorption Behaviour of Nonpolar Molecules on SiO-Adsorbents
| Autor: | H. Stach, J. Jänchen, H. Thamm, E. Stiebitz, R. A. Vetter |
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| Jazyk: | angličtina |
| Rok vydání: | 1986 |
| Předmět: | |
| Zdroj: | Adsorption Science & Technology, Vol 3 (1986) |
| Druh dokumentu: | article |
| ISSN: | 0263-6174 2048-4038 02636174 |
| DOI: | 10.1177/026361748600300407 |
| Popis: | The adsorption equilibrium of n -paraffins (ethane, n -butane, n -hexane and n -decane) and some noble gases on SiO 2 -adsorbents with different pore diameter have been investigated using the techniques of isostere-, isotherm- and calorimetric-measurements. There is a strong influence of the pore diameter on the adsorption potential. As the pore diameter of the adsorbents increases the adsorption enthalpy decreases while the adsorption entropy increases. For the initial heats of adsorption of the n -alkanes an empirical equation is derived, allowing the calculation of the thermodynamic data in advance, knowing the (mean) pore diameter. |
| Databáze: | Directory of Open Access Journals |
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