| Autor: |
Olivia Pabois, Yihui Dong, Nir Kampf, Christian D. Lorenz, James Doutch, Alejandro Avila-Sierra, Marco Ramaioli, Mingduo Mu, Yasmin Message, Evangelos Liamas, Arwen I. I. Tyler, Jacob Klein, Anwesha Sarkar |
| Jazyk: |
angličtina |
| Rok vydání: |
2024 |
| Předmět: |
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| Zdroj: |
Communications Materials, Vol 5, Iss 1, Pp 1-13 (2024) |
| Druh dokumentu: |
article |
| ISSN: |
2662-4443 |
| DOI: |
10.1038/s43246-024-00590-5 |
| Popis: |
Abstract Designing plant protein-based aqueous lubricants can be of great potential to achieve sustainability objectives by capitalising on inherent functional groups without using synthetic chemicals; however, such a concept remains in its infancy. Here, we engineer a class of self-assembled sustainable materials by using plant-based protofilaments and their assembly within a biopolymeric hydrogel giving rise to a distinct patchy architecture. By leveraging physical interactions, this material offers superlubricity with friction coefficients of 0.004-to-0.00007 achieved under moderate-to-high (102-to-103 kPa) contact pressures. Multiscale experimental measurements combined with molecular dynamics simulations reveal an intriguing synergistic mechanism behind such ultra-low friction - where the uncoated areas of the protofilaments glue to the surface by hydrophobic interactions, whilst the hydrogel offers the hydration lubrication. The current approach establishes a robust platform towards unlocking an untapped potential of using plant protein-based building blocks across diverse applications where achieving superlubricity and environmental sustainability are key performance indicators. |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
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