1-Benzoyl-3-methyl-3-pentylthiourea
| Autor: | N. Gunasekaran, P. Jerome, R. Karvembu, Seik Weng Ng, Edward R. T. Tiekink |
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| Jazyk: | angličtina |
| Rok vydání: | 2011 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 67, Iss 5, Pp o1149-o1149 (2011) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S1600536811013365 |
| Popis: | Two independent molecules comprise the asymmetric unit of the title compound, C14H20N2OS. These differ in the relative orientations of the pentyl chains [C—C—C—C torsion angles = −176.7 (3) and 176.4 (3)°]. Significant twists are evident in each molecule, the dihedral angles formed between the thiourea and amide residues being 53.47 (17) and 55.81 (17)°. In the crystal, each molecule self-associates via a centrosymmetric eight-membered {...HNC=S}2 synthon, and these are connected into a supramolecular chain along [110] via C—H...O contacts. Disorder is noted for one of the independent molecules in that two orientations (50:50) were resolved for its benzene ring. |
| Databáze: | Directory of Open Access Journals |
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