Crystal structure of di-μ2-chlorido-bis[(1-aza-4-azoniabicyclo[2.2.2]octane-κN1)dichloridodicadmium]
| Autor: | Jing-Jing Yan, Qi-Jian Pan, Li-Zhuang Chen |
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| Jazyk: | angličtina |
| Rok vydání: | 2015 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E: Crystallographic Communications, Vol 71, Iss 12, Pp m259-m260 (2015) |
| Druh dokumentu: | article |
| ISSN: | 2056-9890 20569890 |
| DOI: | 10.1107/S2056989015023361 |
| Popis: | In the structure of the binuclear title compound, [Cd2(C6H13N2)2Cl6], two CdII atoms are bridged by two Cl− ligands, defining a centrosymmetric Cd2Cl2 motif. Each metal cation is additionally coordinated by two Cl− ligands and the N atom of a protonated 1,4-diazabicyclo[2.2.2]octane (H-DABCO)+ ligand, leading to an overall trigonal–bipyramidal coordination environment with one of the bridging Cl− ligands and the N atom at the apical sites. In the crystal, the neutral dimers are linked via N—H...Cl hydrogen bonds, forming a two-dimensional network expanding parallel to (100). |
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