| Autor: |
Hong-Jyun Huang, Chia-Shuo Hsu, Jin-Ya Huang, Shu-Chih Haw, Han-Yi Chen, Nozomu Hiraoka, Yen-Fa Liao, Chih-Wei Hu |
| Jazyk: |
angličtina |
| Rok vydání: |
2024 |
| Předmět: |
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| Zdroj: |
Journal of Power Sources Advances, Vol 29, Iss , Pp 100155- (2024) |
| Druh dokumentu: |
article |
| ISSN: |
2666-2485 |
| DOI: |
10.1016/j.powera.2024.100155 |
| Popis: |
The comprehensive understanding of the local structural changes surrounding lithium in lithium silicate (LixSiOy) and silicide (LixSi) within Li/SiOx batteries during the reversible structural transformations has been hindered by the limitations of current methodologies. In this work, the evolution of electronic structure at various lithiation stages has been addressed well by examining the Li K-edge spectra through X-ray Raman spectroscopy (XRS). The features observed in the Li K-edge XRS spectra provide insights into the development and alteration of LixSiOy, which emerges in the initial phases and may be accompanied by a reduction in the ionicity of Li–O bonding during lithiation. These features also agree well with the accompanying FDMNES code simulation. The correlation between electrochemical mechanisms and spectral characteristics is further explored by applying pseudo-Voigt peaks and cumulative pseudo-Voigt functions for fitting purposes. The absence of a significant edge shift indicates a similarity in the electronic structure of LixSi throughout lithiation, and no evidence of Li2O formation has also been observed. The Li K-edge XRS spectra exhibit strong agreement with the electrochemical behavior, establishing it as a valuable tool for investigating the evolution of electronic structure in Li/SiOx batteries. |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
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