Decomposition Characteristics and Kinetics of Microalgae in N2 and CO2 Atmospheres by a Thermogravimetry
Autor: | Xu Qing, Ma Xiaoqian, Yu Zhaosheng, Cai Zilin, Ling Changming |
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Jazyk: | angličtina |
Rok vydání: | 2017 |
Předmět: | |
Zdroj: | Journal of Combustion, Vol 2017 (2017) |
Druh dokumentu: | article |
ISSN: | 2090-1968 2090-1976 |
DOI: | 10.1155/2017/6160234 |
Popis: | The thermal degradation characteristics of microalgae were investigated in highly purified N2 and CO2 atmospheres by a thermogravimetric analysis (TGA) under different heating rates (10, 20, and 40°C/min). The results indicated that the total residual mass in CO2 atmosphere (16.86%) was less than in N2 atmosphere (23.12%); in addition, the kinetics of microalgae in N2 and CO2 atmospheres could be described by the pseudo bicomponent separated state model (PBSM) and pseudo-multi-component overall model (PMOM), respectively. The kinetic parameters calculated by Coats-Redfern method showed that, in CO2 atmosphere, the apparent activation energy (E) of microalgae was between 9.863 and 309.381 kJ mol−1 and the reaction order (n) was varied from 1.1 to 7. The kinetic parameters (E,n) of the second stage in CO2 atmosphere were quite similar to those in N2 atmosphere. |
Databáze: | Directory of Open Access Journals |
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