| Autor: |
H. L. B. Boström, S. Bette, S. T. Emmerling, M. W. Terban, B. V. Lotsch |
| Jazyk: |
angličtina |
| Rok vydání: |
2022 |
| Předmět: |
|
| Zdroj: |
APL Materials, Vol 10, Iss 7, Pp 071106-071106-6 (2022) |
| Druh dokumentu: |
article |
| ISSN: |
2166-532X |
| DOI: |
10.1063/5.0091091 |
| Popis: |
We use powder x-ray diffraction under variable temperature to study the thermal expansion of the metal–organic framework (MOF) PCN-222. The thermal expansion increases drastically in magnitude following more aggressive heating, which is rationalized by enhanced flexibility upon guest removal. Moreover, the thermal response strongly depends on the temperature: the volumetric expansivity nearly quadruples and the expansion along c changes sign upon cooling. Our results highlight the large flexibility of MOFs and the role of guest species. |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
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