New Insights into the Role of Weak Electron–Phonon Coupling in Nanostructured ZnO Thin Films

Autor: Ashish C. Gandhi, Wei-Shan Yeoh, Ming-An Wu, Ching-Hao Liao, Dai-Yao Chiu, Wei-Li Yeh, Yue-Lin Huang
Jazyk: angličtina
Rok vydání: 2018
Předmět:
Zdroj: Nanomaterials, Vol 8, Iss 8, p 632 (2018)
Druh dokumentu: article
ISSN: 2079-4991
DOI: 10.3390/nano8080632
Popis: High-quality crystalline nanostructured ZnO thin films were grown on sapphire substrates by reactive sputtering. As-grown and post-annealed films (in air) with various grain sizes (2 to 29 nm) were investigated by scanning electron microscopy, X-ray diffraction, and Raman scattering. The electron–phonon coupling (EPC) strength, deduced from the ratio of the second- to the first-order Raman scattering intensity, diminished by reducing the ZnO grain size, which mainly relates to the Fröhlich interactions. Our finding suggests that in the spatially quantum-confined system the low polar nature leads to weak EPC. The outcome of this study is important for the development of nanoscale high-performance optoelectronic devices.
Databáze: Directory of Open Access Journals