Investigation of Thermal Properties of Zr-Based Metallic Glass–Polymer Composite with the Addition of Silane

Autor: Adit Sharma, Dmitry Muratov, Mikhail Zadorozhnyy, Andrey Stepashkin, Andrey Bazlov, Artem Korol, Ruslan Sergiienko, Victor Tcherdyntsev, Vladislav Zadorozhnyy
Jazyk: angličtina
Rok vydání: 2022
Předmět:
Zdroj: Polymers, Vol 14, Iss 17, p 3548 (2022)
Druh dokumentu: article
ISSN: 2073-4360
DOI: 10.3390/polym14173548
Popis: Composites based on Zr65Cu17.5Ni10Al7.5/PTFE (polytetrafluoroethylene) with silane were prepared by ball milling with subsequent thermal pressing. Silanization was performed in the alcoholic solution with metallic glass powder. Different composites, 30/70 and 50/50 with silane, were prepared. During ball milling, Zr2Cu and Zr2Ni intermetallic phases were formed. The Zr-based metallic glass had a large supercooled region, and the melting point of the 30/70 and 50/50 composites with silane was near to the melting point of PTFE. The 50/50 composite (silane) had the highest thermal conductivity compared to the 30/70 composite samples. The incorporation of silane in metallic glass/polymer was investigated by Fourier-transform infrared spectroscopy (FTIR) and scanning electron microscope (SEM) analysis. Thermogravimetric analysis (TGA) showed the thermal stability of the composite samples up to 450–460 °C. It was also concluded that the 50/50 composite with silane has better thermal stability than the 30/70 composite with silane. The addition of silane in 30/70 and 50/50 composites increased the thermal conductivity compared to the composites without silane.
Databáze: Directory of Open Access Journals
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