Surface and electrochemical corrosion analysis of niobium oxide film formed in various wet media
| Autor: | V.I. Chukwuike, K. Rajalakshmi, R.C. Barik |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2021 |
| Předmět: | |
| Zdroj: | Applied Surface Science Advances, Vol 4, Iss , Pp 100079- (2021) |
| Druh dokumentu: | article |
| ISSN: | 2666-5239 30946980 |
| DOI: | 10.1016/j.apsadv.2021.100079 |
| Popis: | Niobium metal has a wide range of applications in medical devices, nuclear applications, and solar cells. Therefore, niobium corrosion behavior and oxide film formation mechanisms are of great interest. Steady-state polarization and a.c transient techniques were employed to determine the effective capacitance, oxide film thickness, and the corrosion behavior of niobium through the time-constant distribution. In this report, we describe a cost-effective wet chemical method of surface treatment of niobium metal for the study of the metastable oxide film (Nb2O5) formed in different media such as NaCl, NaOH, HCl, and H2SO4 solutions. The investigations confirmed a time-dependent formation and dissolution of a protective oxide layer in all the tested media at different potentials, however, recommends short immersion time ( 1 h for NaCl and NaOH. The work developed a new understanding of the niobium corrosion behavior through effective capacitance and film morphology. |
| Databáze: | Directory of Open Access Journals |
| Externí odkaz: |
|