The continuous synthesis and application of graphene supported palladium nanoparticles: a highly effective catalyst for Suzuki-Miyaura cross-coupling reactions

Autor: Brinkley Kendra W., Burkholder Michael, Siamaki Ali R., Belecki Katherine, Gupton B. Frank
Jazyk: angličtina
Rok vydání: 2015
Předmět:
Zdroj: Green Processing and Synthesis, Vol 4, Iss 3, Pp 241-246 (2015)
Druh dokumentu: article
ISSN: 2191-9542
2191-9550
DOI: 10.1515/gps-2015-0021
Popis: An efficient, sustainable, and continuous method for the preparation of graphene supported palladium nanoparticles (Pd/G) has been developed using microwave irradiation as a heating source for the metal deposition process. The Pd/G produced from this method was effective in Suzuki-Miyaura cross-coupling reactions with a broad range of substrates. When incorporated into a packed bed flow reactor, this ligand free catalyst system continued to demonstrate high reaction conversions with limited catalyst leaching in the reaction mixture (347 ppb palladium).
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