The continuous synthesis and application of graphene supported palladium nanoparticles: a highly effective catalyst for Suzuki-Miyaura cross-coupling reactions
Autor: | Brinkley Kendra W., Burkholder Michael, Siamaki Ali R., Belecki Katherine, Gupton B. Frank |
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Jazyk: | angličtina |
Rok vydání: | 2015 |
Předmět: | |
Zdroj: | Green Processing and Synthesis, Vol 4, Iss 3, Pp 241-246 (2015) |
Druh dokumentu: | article |
ISSN: | 2191-9542 2191-9550 |
DOI: | 10.1515/gps-2015-0021 |
Popis: | An efficient, sustainable, and continuous method for the preparation of graphene supported palladium nanoparticles (Pd/G) has been developed using microwave irradiation as a heating source for the metal deposition process. The Pd/G produced from this method was effective in Suzuki-Miyaura cross-coupling reactions with a broad range of substrates. When incorporated into a packed bed flow reactor, this ligand free catalyst system continued to demonstrate high reaction conversions with limited catalyst leaching in the reaction mixture (347 ppb palladium). |
Databáze: | Directory of Open Access Journals |
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