| Autor: |
LIU Yue, LIU Qi, ZHU Jia-hui, ZHANG Hong-sen, WANG Jun |
| Jazyk: |
čínština |
| Rok vydání: |
2022 |
| Předmět: |
|
| Zdroj: |
He huaxue yu fangshe huaxue, Vol 44, Iss 3, Pp 285-298 (2022) |
| Druh dokumentu: |
article |
| ISSN: |
0253-9950 |
| DOI: |
10.7538/hhx.2022.YX.2021078 |
| Popis: |
In order to design an adsorption material with higher selectivity to U(Ⅵ) while ensuring a higher adsorption capacity, g-C3N4 and ammonium dihydrogen phosphate were used as raw materials to prepare P-C3N4 by thermal copolymerization. The Ag3PO4/P-C3N4 composite adsorption material was prepared by in-situ co-precipitation method using disodium hydrogen phosphate and silver nitrate. The results of adsorption experiments show that the adsorption capacity of Ag3PO4/P-C3N4 composite adsorbent for U(Ⅵ) reaches 524.6 mg/g at room temperature; the distribution coefficient to U(Ⅵ) reaches 6.13×103 mL/g with competing ions such as Na+, K+, Mg2+, Ca2+, Sr2+, Zn2+, Ni2+ and Co2+ in solution. XPS analysis result shows that the N- and P-containing functional groups in the Ag3PO4/P-C3N4 composite adsorption material may participate in the U(Ⅵ) adsorption process. Therefore, the Ag3PO4/P-C3N4 composite adsorption material is one kind of adsorption material with higher adsorption capacity and higher U(Ⅵ) selectivity. |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
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