Unprecedented Coordination-Induced Bright Red Emission from Group 12 Metal-Bound Triarylazoimidazoles

Autor: Artyom A. Astafiev, Olga V. Repina, Boris S. Tupertsev, Alexey A. Nazarov, Maria R. Gonchar, Anna V. Vologzhanina, Valentine G. Nenajdenko, Andreii S. Kritchenkov, Victor N. Khrustalev, Victor N. Nadtochenko, Alexander G. Tskhovrebov
Jazyk: angličtina
Rok vydání: 2021
Předmět:
Zdroj: Molecules, Vol 26, Iss 6, p 1739 (2021)
Druh dokumentu: article
ISSN: 1420-3049
DOI: 10.3390/molecules26061739
Popis: Arylazoimidazoles are important dyes which were intensively studied in the past. In contrast, triarylazoimidazoles (derivatives which carry aryl substituents at the imidazole core) received almost no attention in the scientific literature. Here, we report a new family of simple and easily accessible triarylazoimidazole-group 12 metal complexes, which feature highly efficient photo-luminescence emission (Φ up to 0.44). Novel compounds exhibit bright red emission in solution, which could be excited with a visible light.
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