Optimization of Influential Parameters for the Degradation of Metronidazole Contained in Aquaculture Effluent via Sonocatalytic Process: Kinetics and Mechanism
| Autor: | O.H. Aremu, C.O. Akintayo, S.M. Nelana, M.J. Klink and O.S. Ayanda |
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| Jazyk: | angličtina |
| Rok vydání: | 2022 |
| Předmět: | |
| Zdroj: | Nature Environment and Pollution Technology, Vol 21, Iss 4, Pp 1875-1885 (2022) |
| Druh dokumentu: | article |
| ISSN: | 0972-6268 2395-3454 |
| DOI: | 10.46488/NEPT.2022.v21i04.042 |
| Popis: | This study examined the synthesis of a viable catalyst for the degradation of metronidazole contained in aquaculture effluent. Zinc oxide nanoparticles (n-ZnO) were synthesized via the precipitation method and calcined at 500oC in a muffle furnace to enhance the degradability properties. The morphology showed a hexagonal structure with an average particle size of 71.48 nm and the elemental composition showed a higher weight percent of 59.15% for zinc and 21.65% for oxygen. The FTIR confirms the vibrational characteristic mode of the Zn-O band at 427.21cm-1. The XRD showed a good crystallinity and the BET surface area was 8.58 m2.g-1 which showed that the n-ZnO possesses more active sites that can remove pollutants from wastewater. However, no studies have been done on the removal of MNZ in aquaculture effluent. The kinetics followed pseudo-second-order kinetics and the Langmuir-Hinshelwood model best fit the degradation process with R2, Kc, and KLH values of 0.96781, 1.486 × 10-1 mg. Lmin-1) and 8.790 × 10-2 (L.mg-1). Under the influential parameters, the percentage COD removal achieved for MNZ in aquaculture effluent was 62.6%, 89.8%, and 98.5% of MNZ at 20% ultrasonic amplitude, 5 mL 2% H2O2 and 0.02g n-ZnO within 60 min sonication time for US only, US/n-ZnO and US/n-ZnO/H2O2 systems. Hence, MNZ contained in aquaculture effluent can best be degraded with the synergetic effect of the US/n-ZnO/ H2O2 system. |
| Databáze: | Directory of Open Access Journals |
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