Crystal structure of trans-dichlorido(4-nitroaniline-κN1)(piperidine-κN)platinum(II)
| Autor: | Chi Nguyen Thi Thanh, Truong Hoang Van, Thong Pham Van, Ngan Nguyen Bich, Luc Van Meervelt |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2015 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E: Crystallographic Communications, Vol 71, Iss 6, Pp 644-646 (2015) |
| Druh dokumentu: | article |
| ISSN: | 2056-9890 20569890 |
| DOI: | 10.1107/S2056989015009196 |
| Popis: | In the title complex, [PtCl2(C5H11N)(C6H6N2O2)], the PtII metal atom displays a slightly distorted trans-PtN2Cl2 square-planar coordination geometry. The dihedral angle between the mean plane of the benzene and piperidine rings is 89.03 (3)°. In the crystal structure, inversion dimers are formed via N—H...Cl hydrogen-bond interactions, resulting in chains parallel to the [001] direction. The benzene rings within the chains show π–π stacking interactions [centroid-to-centroid distances of 3.801 (3) Å] and neighbouring chains interact via N—H...O hydrogen bonds. |
| Databáze: | Directory of Open Access Journals |
| Externí odkaz: |
|