1,1′-{(Hexane-1,6-diyl)bis[(azaniumylylidene)methanylylidene]}bis(naphthalen-2-olate)

Autor: Kamel Ouari, Sabrina Bendia, Moufida Merzougui, Corinne Bailly
Jazyk: angličtina
Rok vydání: 2015
Předmět:
Zdroj: Acta Crystallographica Section E: Crystallographic Communications, Vol 71, Iss 1, Pp o51-o52 (2015)
Druh dokumentu: article
ISSN: 2056-9890
20569890
DOI: 10.1107/S2056989014027236
Popis: The whole molecule of the title Schiff base compound, C28H28N2O2, is generated by inversion symmetry. It is formed from two units of ortho-hydroxynaphthaldehyde bridged with 1,6-diaminohexane. The N atoms are protonated and, thus, the structure is a bis-zwitterionic compound in the solid state. The zwitterion shows strong intramolecular N—H...O hydrogen bonds between the iminium N and the naphthalenolate O atoms.
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