A practical approach for the calculation of the activation energy of the sintering

Autor: Pouchly Vaclav, Hruby Jan, Maca Karel
Jazyk: angličtina
Rok vydání: 2016
Předmět:
Zdroj: Science of Sintering, Vol 48, Iss 3, Pp 317-324 (2016)
Druh dokumentu: article
ISSN: 0350-820X
1820-7413
DOI: 10.2298/SOS1603317P
Popis: Newly developed software for calculation of activation energy (Qs in the following) of sintering using the Wang and Raj model is presented. To demonstrate the practical potential of the software and to evaluate the behaviour of the Qs during the sintering process, alumina and cubic zirconia ceramic compacts were prepared from nanometric powders. The results obtained with both materials are in agreement with previously published data calculated by different approaches. In the interval of interest (relative densities from 60 % to almost 100 % of theoretical density), both materials show similar behaviour. Three distinct regions can be seen: the initial constant values of Qs 868 kJ/mol and 762 kJ/mol for alumina and cubic zirconia, respectively; a region containing linear drop of Qs and the final region of constant Qs values 625 kJ/mol and 645 kJ/mol for alumina and cubic zirconia, respectively.
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