Biomimetic Iodofunctionalization of Aromatic and Heteroaromatic Compounds Catalyzed by Selenium Tetrachloride

Autor: Beatriz C. O. Rocha, Givago P. Perecim, Cristiano Raminelli
Jazyk: angličtina
Rok vydání: 2019
Předmět:
Zdroj: SynOpen, Vol 03, Iss 04, Pp 142-147 (2019)
Druh dokumentu: article
ISSN: 2509-9396
DOI: 10.1055/s-0039-1690337
Popis: Abstract A biomimetic iodofunctionalization of aromatic and heteroaromatic compounds has been developed using NaI as a source of iodine and 30% H2O2 as a mild oxidant, as well as SeCl4 as a commercially available catalyst in water without a co-solvent. The method affords iodinated compounds in isolated yields of 37 to 99%. The catalytic system has potential for the bromination of aromatic substrates.
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