Development of an All Solid State Battery Incorporating Graphene Oxide as Proton Conductor

Autor: Yuta Shudo, Md. Saidul Islam, Mohammad Razaul Karim, Nurun Nahar Rabin, Kosuke Wakata, Ryo Ohtani, Masaaki Nakamura, Leonard F. Lindoy, Shinya Hayami
Jazyk: angličtina
Rok vydání: 2017
Předmět:
Zdroj: Global Challenges, Vol 1, Iss 6, Pp n/a-n/a (2017)
Druh dokumentu: article
ISSN: 2056-6646
DOI: 10.1002/gch2.201700054
Popis: Graphene oxide (GO) shows high proton conductivity (≈10−4 Scm−1), excellent mechanical stability, and electrical insulation property, which makes it an ideal candidate for use as a proton conducting solid state electrolyte. The prospects of using GO as single phase solid electrolyte in an all solid battery is presented herein. A battery with the cell configuration: Zn + ZnSO4•7H2O + graphite (anode) || GO (electrolyte) || MnO2 + graphite (cathode) is fabricated. Cyclic voltammetry confirms its rechargeable nature. The respective discharge capacity and power density of the cell are 360 μAh and 19.5 mW kg−1 at a constant current drain of 3 μA under the experimental conditions employed. GO based proton conductors are cleaner and cheaper than other solid electrolytes. The current study strongly suggests that GO can be used as a practical and beneficial component in solid state battery applications with low energy feedback.
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