Synthesis and photophysical properties of new reactive fluorophenanthrenes

Autor: Hajri, Amira K., Albalawi, Marzough A., Elsayed, Nadia H., Aloui, Faouzi
Jazyk: English<br />French
Rok vydání: 2020
Předmět:
Zdroj: Comptes Rendus. Chimie, Vol 23, Iss 4-5, Pp 315-327 (2020)
Druh dokumentu: article
ISSN: 1878-1543
DOI: 10.5802/crchim.29
Popis: A series of six new suitably functionalized fluorophenanthrene derivatives were synthesized through a simple procedure, making use of inexpensive starting materials under mild conditions. The target phenanthrenes were characterized by 1H and 13C NMR and FT-IR spectroscopies. UV–Vis absorption and photoluminescence of these phenanthrenes were evaluated in solutions. A notable behavior and a strong fluorescence in the blue region of the visible spectrum were observed, making them potential candidates for organic light-emitting diode technology or advanced materials. Their electrochemical behavior was also experimentally examined in solution, demonstrating an important charge transfer interaction owing to their ${\pi }$-conjugated electronic system.
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