Role of the coupling of the electronic transitions on the order of the metal-to-insulator phase transition in nickelates

Autor: Lucia Varbaro, Lukas Korosec, Chih-Ying Hsu, Duncan T. L. Alexander, Nicolas Jaouen, Jean-Marc Triscone
Jazyk: angličtina
Rok vydání: 2024
Předmět:
Zdroj: APL Materials, Vol 12, Iss 8, Pp 081120-081120-6 (2024)
Druh dokumentu: article
ISSN: 2166-532X
DOI: 10.1063/5.0221334
Popis: Rare-earth nickelates (chemical formula RNiO3, R being a rare-earth cation) display a temperature-dependent metal-to-insulator transition (MIT) together with a breathing distortion of the NiO6 octahedra units at a temperature ranging from 0 to 600 K depending on the size of the R cation. Their rich phase diagram is also characterized by a paramagnetic to antiferromagnetic transition that occurs at the same temperature as the MIT for R = Pr, Nd, while it arises at lower temperatures for all the other members of the series. In this work, we have investigated the order of the MIT in a portion of the phase diagram spanning from SmNiO3 to NdNiO3 by means of temperature dependent transport measurements and resonant elastic x-ray scattering performed on high quality epitaxial SmxNd1−xNiO3 solid solution thin films. Our results show that the order of the metal-to-insulator transition does not depend on whether or not the MIT is coupled with the magnetic transition.
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